Cyclic Voltammetry Simulator
Cyclic Voltammetry Simulator Cyclic Voltammetry Simulator - Basics of Cyclic Voltammetry Theoretical • Semi-infinite planar diffusion • Nicholson–Shain convolution • Butler–Volmer kinetics • IUPAC sign convention Dr. M Kanagasabapathy Associate Professor of Chemistry Rajapalayam Rajus' College Madurai Kamaraj University Rajapalayam, (TN) 626117, India CV Simulation Scan Rate Overlay Randles–Ševčík (ip vs √ν) Concentration Plot (ip vs C) Theory & Equations Input Parameters Formal Reduction Potential E°' (V vs ref) Centre of CV | Fe³⁺/Fe²⁺ ≈ 0.77 V | Ferrocene ≈ 0.40 V Concentration C (mol/L) 1 mM = 0.001 | 10 mM = 0.01 | ip ∝ C (linear) Electrons Transferred (n) Integer 1–8 | ΔEp = 59.16/n mV at 298 K ...